Formation of mesoscopic water networks in aqueous systems.

نویسندگان

  • Lívia B Pártay
  • Pál Jedlovszky
  • Ivan Brovchenko
  • Alla Oleinikova
چکیده

Formation of the macroscopically-infinite hydrogen-bonded water network in various aqueous systems occurs via 3D percolation transition when the probability of finding a spanning water cluster exceeds 95%. As a result, in a wide interval of water content below the percolation threshold, rarefied quasi-2D water networks span over the mesoscopic length scale. Formation and topology of spanning water networks, which affect various properties of aqueous systems, can be described within the framework of the percolation theory.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Prediction of Hydrate Formation for the Systems Containing Single and Mixed Electrolyte Solutions

In this work the effect of electrolytes on hydrate formation was investigated. To do so, a new model was used in predicting the hydrate formation conditions in presence of both single and mixed electrolyte solutions. The new model is based on the van der Waals - Platteeuw hydrate equation of state. In order to evaluate the values for the activity of water in electrolyte solutions t...

متن کامل

Probabilistic Contaminant Source Identification in Water Distribution Infrastructure Systems

Large water distribution systems can be highly vulnerable to penetration of contaminant factors caused by different means including deliberate contamination injections. As contaminants quickly spread into a water distribution network, rapid characterization of the pollution source has a high measure of importance for early warning assessment and disaster management. In this paper, a methodology...

متن کامل

The experimental study of reverse micellar phase in AOT/ Heptane/ (Water or aqueous) as nano template

In this paper electrical conductivity measurements and optical investigations takes place in AOT/ heptane/ (water or aqueous) systems. The water in oil system prepared with adding water in 50% by weight of AOT/ heptane solution.  In other systems instead of water, aqueous solutions of 1) zinc acetate and water 2) Potassium Hydroxide and water were used. In each phase, the trend of the electrica...

متن کامل

The experimental study of reverse micellar phase in AOT/ Heptane/ (Water or aqueous) as nano template

In this paper electrical conductivity measurements and optical investigations takes place in AOT/ heptane/ (water or aqueous) systems. The water in oil system prepared with adding water in 50% by weight of AOT/ heptane solution.  In other systems instead of water, aqueous solutions of 1) zinc acetate and water 2) Potassium Hydroxide and water were used. In each phase, the trend of the electrica...

متن کامل

Solvent Effects on Complexation of Dioxovanadium (V) with Glycine in Methanol-Water Mixtures

The formation constants of the species formed in the systems fr + glycine + dioxovanadium(V) + and H+ + glycine have been determined in aqueous solutions of methanol at 25 °C and constant ionicstrength, using spectrophotometric and potentiometric techniques. It was shown thatdioxovanadium(V) forms two mononuclear 1 : land 1:2 complexes with glycine. The formationconstants in various media were ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 9 11  شماره 

صفحات  -

تاریخ انتشار 2007